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Force constants may be calculated on the basis of observed spectra or by quantumchemical methods. They are heavily dependent on the definition of the force field used for the calculation (see Sec. 5.2). However, for estimations of the general behavior of the observed frequencies, the simple valence force field SVFF, (compare Sec. 5.2) is sufficient. It takes into account the force constants of bond stretchings and different kinds of angle deformations. It neglects interaction force constants which describe the changes of the elastic properties of one bond when others are deformed. The stretching force constants have values between 1 and 25 N/cm. They are tabulated in the books cited in the second paragraph of Sec. 2.5. Siebert (1966) found an equation which allows approximate calculation of force constants of any single bond: (2.5- 14) Here, Z, are the atomic numbers and n, are the principal quantum numbers of its valence electrons. The force constant for a C-C single bond is calculated to be 4.05 N/cm, the experimental value is 4.45 N/cm. Siebert also describes the relation between the force constantfN of a multiple bond of the order N to that of a single bondfl and the lengths TN and 1-1 of these bonds: (2.5- 15) word pdf 417 How to Encode a Tab or Function in a PDF417 in Microsoft Word ...
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